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Abstract:
Helium-Neon, nitrogen, and dye lasers are used in undergraduate pedagogy to
conduct first-generation laser experiments. Nd:YAG lasers, with high pulse energy and
superior beam quality, have paved the way for second-generation laser experiments. The
departments of chemistry and physics are taking the vital step of incorporating
second-generation laser experiments into their laboratory curriculum by using Nd:YAG
lasers. Six advanced laser experiments are introduced initially as research projects and
later, as regular experiments, into their laboratory courses. The integrated use of
Nd:YAG, YAG pumped dye lasers and a FTIR spectrometer facilitates a wide range of advanced
experiments for undergraduates, covering the areas of gas-phase, non-linear, and
low-temperature spectroscopy. The experiments include stimulated Raman scattering of H2,
D2, N2 and O2, coherent anti-Stokes Raman scattering of
air, time-resolved laser-induced fluorescence of OH radicals in flame, low-temperature
matrix assisted photolysis of organometallics, photo-reduction of benzophenone, and
conventional Raman and IR spectroscopy of organic molecules. Most of them use a computer
interface, boxcar averager and pre-amplifier along with the physics departments
monochromator, and photomultiplier tube to scan, collect and analyze the spectral data.
This exposes our students to modern advanced lasers and to computer-based data acquisition
techniques in a non-black box learning environment. Collectively, these experiments
upgrade our optics laboratory, thereby enhancing our optics curriculum and
curricula in physical, organic,
inorganic chemistry courses.
Proposed New Laser Experiments
| Physical Chemistry (Fall semester) and Optics (Spring semester) |
1. Conventional Raman (CRS) and IR Spectroscopy of Organic Molecules
2. Stimulated Raman Scattering (SRS) of H2, D2, N2, O2,
and CH4
3. Coherent Anti-Stokes Raman Scattering (CARS) Spectrum of Air
4. Laser-Induced Fluorescence (LIF) of OH radical in flame |
| Organic Chemistry (Spring semester) |
5. Photolysis of Benzophenone (spring) |
| Inorganic Chemistry (Spring semester) |
6. Low Temperature Matrix Assisted Photolysis (LTMAP) of Organometallic
Complexes |
Time line for Project Implementation
Year |
Summer |
Fall |
Spring |
2000 |
- Purchase of laser (Nd:YAG), optics, electronic accessories and
FTIR spectrometer
- Set up laser lab with under- graduate research assistants
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- Experiments (1), (5) and (6) as research projects in physical
chemistry lab
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- Web page construction, creation of list server
- Lab procedures written & published in the Journal of Student Research (local)
- Implementation of experiments in regular labs
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2001 |
- Purchase of Dye laser
- Refinement of lab procedure for experiments (1), (5) & (6)
- Continuation of web page construction
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- Experiments (2), (3) & (4) as research projects in physical chemistry lab
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- Implementing experiments in regular labs
- Undergraduate student presentations at conferences
- Project report available to other institution on request (with experimental procedure
& implementation details)
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2002 |
- Completion of Web page
- Refinements of lab procedure for all the experiments by PI
- Possible new experiments
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- Revision of experimental procedures based on results from other institutions
- Manuscript write ups for peer-reviewed journals
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Major Instruments Used in this
Project
(1) Pulsed Nd:YAG laser (1064, 532, 355, and 266 nm) from Continuum, Surelite II
series
(2) YAG pumped Dye laser from Continuum, ND6000 with frequency doubling crystal for
scannable UV region
(3) Raman Shifter from Light Age, Inc.
(4) FTIR Spectrometer from Nicolet, Avatar 320 model with spectral search
libraries
(5) UV and Visible optics and optical mounts
(6) Electronics and computer accessories for nanosecond signal collection and
manipulation
Student Workers
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Summer 2000: Undergraduate student workers Tom Davey and Chad Thompson |
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Tom Davey photolyzing benzophenone using 355 nm from a frequency tripled Nd:YAG laser |
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Tom Davey checking the IR spectrum for the benzpinacol product |
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