Department of Physics/Science


[Home]  [D. Bahr]  [Up]


 

 

Second-Generation Laser Experiments In Undergraduate Laboratories 
Abstract: Helium-Neon, nitrogen, and dye lasers are used in undergraduate pedagogy to conduct first-generation laser experiments. Nd:YAG lasers, with high pulse energy and superior beam quality, have paved the way for second-generation laser experiments. The departments of chemistry and physics are taking the vital step of incorporating second-generation laser experiments into their laboratory curriculum by using Nd:YAG lasers. Six advanced laser experiments are introduced initially as research projects and later, as regular experiments, into their laboratory courses. The integrated use of Nd:YAG, YAG pumped dye lasers and a FTIR spectrometer facilitates a wide range of advanced experiments for undergraduates, covering the areas of gas-phase, non-linear, and low-temperature spectroscopy. The experiments include stimulated Raman scattering of H2, D2, N2 and O2, coherent anti-Stokes Raman scattering of air, time-resolved laser-induced fluorescence of OH radicals in flame, low-temperature matrix assisted photolysis of organometallics, photo-reduction of benzophenone, and conventional Raman and IR spectroscopy of organic molecules. Most of them use a computer interface, boxcar averager and pre-amplifier along with the physics department’s monochromator, and photomultiplier tube to scan, collect and analyze the spectral data. This exposes our students to modern advanced lasers and to computer-based data acquisition techniques in a non-black box learning environment. Collectively, these experiments upgrade our optics laboratory, thereby enhancing our optics curriculum and curricula in physical, organic, inorganic chemistry courses. 

Proposed New Laser Experiments   

Physical Chemistry (Fall semester) and Optics (Spring semester) 1. Conventional Raman (CRS) and IR Spectroscopy of Organic Molecules 
2. Stimulated Raman Scattering (SRS) of H2, D2, N2, O2, and CH4 
3. Coherent Anti-Stokes Raman Scattering (CARS) Spectrum of Air 
4. Laser-Induced Fluorescence (LIF) of OH radical in flame
Organic Chemistry (Spring semester) 5. Photolysis of Benzophenone (spring)
Inorganic Chemistry (Spring semester) 6. Low Temperature Matrix Assisted Photolysis (LTMAP) of Organometallic Complexes 

 


Time line for Project Implementation  
  

Year

Summer

Fall

Spring

2000

  • Purchase of laser (Nd:YAG), optics, electronic accessories and FTIR spectrometer
  • Set up laser lab with under- graduate research assistants
  • Experiments (1), (5) and (6) as research projects in physical chemistry lab
  • Web page construction, creation of list server 
  • Lab procedures written & published in the Journal of Student Research (local)
  • Implementation of experiments in regular labs

 

  2001

  • Purchase of Dye laser
  • Refinement of lab procedure for experiments (1), (5) & (6)
  • Continuation of web page construction

 

  • Experiments (2), (3) & (4) as research projects in physical chemistry lab
  • Implementing experiments in regular labs 
  • Undergraduate student presentations at conferences 
  • Project report available to other institution on request (with experimental procedure & implementation details)

 

2002

  • Completion of Web page
  • Refinements of lab procedure for all the experiments by PI
  • Possible new experiments

 

  • Revision of experimental procedures based on results from other institutions
  • Manuscript write ups for peer-reviewed journals

 

 

    


Major Instruments Used in this Project  
(1) Pulsed Nd:YAG laser (1064, 532, 355, and 266 nm) from Continuum, Surelite II series 
(2) YAG pumped Dye laser from Continuum, ND6000 with frequency doubling crystal for scannable UV region 
(3) Raman Shifter from Light Age, Inc. 
(4) FTIR Spectrometer from Nicolet, Avatar 320 model with spectral search libraries 
(5) UV and Visible optics and optical mounts 
(6) Electronics and computer accessories for nanosecond signal collection and manipulation 


 Student Workers 
 

Summer 2000: Undergraduate student workers Tom Davey and Chad Thompson 

 

Tom Davey photolyzing benzophenone using 355 nm from a frequency tripled Nd:YAG laser

 

Tom Davey checking the IR spectrum for the benzpinacol product